On the basicity of ozone

被引：10

作者：

Mariey, L

Lamotte, J

Hoggan, P

Lavalley, JC

Boulanine, K

Tsyganenko, A

机构：

[1] UNIV CAEN, ISMRA, CNRS, UMR 6506, LAB CATALYSE & SPECTROCHIM, F-14050 CAEN, FRANCE

[2] ST PETERSBURG STATE UNIV, INST PHYS, ST PETERSBURG 198904, RUSSIA

来源：

CHEMISTRY LETTERS | 1997年 / 08期

关键词：

D O I：

10.1246/cl.1997.835

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Comparison of IR spectra of species formed from adsorption of different bases on the acidic OH groups of zeolites (KY, MFI) indicates that O-3 basicity is close to that of CO. Calculations confirm such a result; in particular they involve that the terminal oxygen atoms of ozone are the basic centers.

引用

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页码：835 / 836

页数：2

相关论文

共 9 条

[1] CO INTERACTION WITH THE SURFACE OF THERMALLY ACTIVATED CAO AND MGO [J].

BABAEVA, MA ;

BYSTROV, DS ;

KOVALGIN, AY ;

TSYGANENKO, AA .

JOURNAL OF CATALYSIS, 1990, 123 (02) :396-416

[2] LOW-TEMPERATURE CO ADSORPTION ON NA-ZSM-5 ZEOLITES - AN FTIR INVESTIGATION [J].

BORDIGA, S ;

PLATERO, EE ;

AREAN, CO ;

LAMBERTI, C ;

ZECCHINA, A .

JOURNAL OF CATALYSIS, 1992, 137 (01) :179-185

[3] IR STUDY OF OZONE ADSORPTION ON SIO2 [J].

BULANIN, KM ;

ALEXEEV, AV ;

BYSTROV, DS ;

LAVALLEY, JC ;

TSYGANENKO, AA .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (19) :5100-5103

[4] Gas phase ozone decomposition catalysts [J].

Dhandapani, B ;

Oyama, ST .

APPLIED CATALYSIS B-ENVIRONMENTAL, 1997, 11 (02) :129-166

[5]

Knozinger H., 1976, HYDROGEN BOND, V3, P1265

[6] DETERMINATION OF PROTON AFFINITY OF ZEOLITES AND ZEOLITE-LIKE SOLIDS BY LOW-TEMPERATURE ADSORPTION OF CARBON-MONOXIDE [J].

KUBELKOVA, L ;

BERAN, S ;

LERCHER, JA .

ZEOLITES, 1989, 9 (06) :539-543

[7] MOLECULAR-MODELS IN ABINITIO STUDIES OF SOLIDS AND SURFACES - FROM IONIC-CRYSTALS AND SEMICONDUCTORS TO CATALYSTS [J].

SAUER, J .

CHEMICAL REVIEWS, 1989, 89 (01) :199-255

[8] OPTIMIZATION OF PARAMETERS FOR SEMIEMPIRICAL METHODS .1. METHOD [J].

STEWART, JJP .

JOURNAL OF COMPUTATIONAL CHEMISTRY, 1989, 10 (02) :209-220

[9]

THOMAS K, UNPUB CATAL LETT