Poly(fluorenevinylene) derivative by Gilch polymerization for light-emitting diode applications

被引：119

作者：

Jin, SH ^{[1
]}

Park, HJ

Kim, JY

Lee, K

Lee, SP

Moon, DK

Lee, HJ

Gal, YS

机构：

[1] Pusan Natl Univ, Dept Chem Educ, Pusan 609735, South Korea

[2] Pusan Natl Univ, Dept Phys, Pusan 609735, South Korea

[3] Hanwha Chem Res & Dev Ctr, Taejon 305340, South Korea

[4] Zen Photon, Daeduk Gu 306230, Daejon, South Korea

[5] Kyungil Univ, Coll Gen Educ, Polymer Chem Lab, Hayang 712701, South Korea

来源：

MACROMOLECULES | 2002年 / 35卷 / 20期

关键词：

D O I：

10.1021/ma020671c

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of poly(9,9-di-n-octylfluorene-2,7-vinylene) (PFV) via Gilch polymerization together with its characterization and purification using membrane technology was reported. The purity and structure of the monomer were confirmed by 1H NMR , 13C NMR, and elemental analyses. The key factor for obtaining the high molecular weight of the PFV was the introduction of a chloromethyl group into the 9,9-di-n-octylfluorene unit. The optical absorption (Abs) and photoluminescence (PL) spectra of the thin PFV film were obtained.

引用

页码：7532 / 7534

页数：3

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