NMR evaluation of the configurational stability of Cu(I) complexes

被引：51

作者：

Desvergnes-Breuil, V

Hebbe, V

Dietrich-Buchecker, C

Sauvage, JP

Lacour, J

机构：

[1] Univ Strasbourg, Inst Le Bel, Fac Chim, Lab Chim Organominerale,UMR CNRS 7513, F-67070 Strasbourg, France

[2] Univ Geneva, Dept Chim Organ, CH-1211 Geneva 4, Switzerland

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 02期

关键词：

D O I：

10.1021/ic0259890

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Association of chiral [CuL2](+) complexes (L = 2-R-phen, 6-R-bpy, and 2-iminopyridine) with TRISPHAT (tris(tetrachlorobenzene-diolato)phosphate(V)) anion leads to NMR enantiodifferentiation, which can be used to determine the kinetics of racemization of the complexes.

引用

页码：255 / 257

页数：3

共 20 条

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