An alkyl-palladium(II) complex with a bidentate phosphine ligand:: [1,3-bis(diphenylphosphino)propane-P,P′]dimethylpalladium(II) toluene hemisolvate

被引：3

作者：

Abu-Surrah, AS

Debaerdemaeker, T

Huhn, W

Rieger, B

Klinga, M

Repo, T

Leskelä, M

机构：

[1] Univ Helsinki, Dept Chem, Inorgan Chem Lab, FIN-00014 Helsinki, Finland

[2] Univ Ulm, Sekt Rontgen & Elektronenbeugung, D-89069 Ulm, Germany

[3] Univ Ulm, D-89081 Ulm, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷

关键词：

D O I：

10.1107/S0108270100000391

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, [Pd(CH3)(2)(C27H26P2)]. 0.5C(7)H(8), the Pd atom is at the centre of an approximately square-planar arrangement of two P atoms and two methyl groups. The P-Pd-P angle [93.19 (3)degrees] is significantly larger than that in the corresponding dichloride complex [Pd(dppp)Cl-2]. The toluene molecule is disordered across an inversion centre.

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页码：E42 / E43

页数：2

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