Catalytic C-H amination: recent progress and future directions

被引：681

作者：

Collet, Florence ^{[1
]}

Dodd, Robert H. ^{[1
]}

Dauban, Philippe ^{[1
]}

机构：

[1] CNRS, Inst Chim Subst Nat, UPR 2301, F-91198 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 34期

关键词：

N BOND FORMATION; ENANTIOSELECTIVE INTRAMOLECULAR AMIDATION; CHIRAL DIRHODIUM(II) CARBOXYLATES; NITROGEN-ATOM-TRANSFER; OXIDATIVE FUNCTIONALIZATION; EFFICIENT SYNTHESIS; SULFAMATE ESTERS; STEREOSELECTIVE-SYNTHESIS; INTERMOLECULAR AMINATION; MANGANESE-PORPHYRINS;

D O I：

10.1039/b905820f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Recent developments in catalytic C-H amination are discussed in this feature article. The careful design of reagents and catalysts now provides efficient conditions for exquisitely selective intramolecular as well as intermolecular nitrene C-H insertion. The parallel emergence of C-H activation/amination reactions opens new opportunities complementary to those offered by nitrenes.

引用

页码：5061 / 5074

页数：14

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