Thermal condensation of trinuclear lanthanide butoxides.: Molecular structure of La5 (μ5-O) (μ3-OtBu)4(μ-OtBu)4(OtBu)5

被引：40

作者：

Daniele, S

Hubert-Pfalzgraf, LG

Hitchcock, PB

Lappert, MF

机构：

[1] Univ Lyon 1, IRC, F-69626 Villeurbanne, France

[2] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 05期

关键词：

lanthanide complexes; oxo complexes; alkoxide complexes; yttrium; crystal structures;

D O I：

10.1016/S1387-7003(00)00051-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Refluxing of Ln(3)((OBu)-Bu-t)(9)((BuOH)-Bu-t)(2) (Ln=La, Nd, Yb) in toluene led to Ln(5)O((OBu)-Bu-t)(13) which was characterised by X-ray diffraction in the case of lanthanum. Aggregates of higher nuclearity were obtained in similar conditions for yttrium and praseodymium. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：218 / 220

页数：3

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