Preparation and performance of high-impact polystyrene (HIPS)/Nano-Tio2 nanocomposites

被引:91
作者
Zhang, JZ [1 ]
Wang, X [1 ]
Lu, LD [1 ]
Li, D [1 ]
Yang, XJ [1 ]
机构
[1] Nanjing Univ Sci & Technol, Mat Chem Lab, Nanjing 210094, Peoples R China
关键词
high-impact polystyrene (HIPS); nano-TiO2; nanocomposites; dispersions; performance;
D O I
10.1002/app.11302
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
High-impact polystyrene (HIPS) /nano-TiO2 nanocomposites were prepared by surface pretreatment of nano-TiO2 with special structure dispersing agent (TAS) and master batch manufacturing technology. The results show that when the nano-TiO2 content is 2%, the notched impact strength, tensile strength, and elastic modulus of HIPS/ nano-TiO2 nanocomposites increased to a maximum. This result indicates that nano-TiO2 has both toughening and reinforcing effects on HIPS. The heat-deflection temperature and flame-retardance of HIPS/nano-TiO2 nanocomposites are also obviously improved as the nano-TiO2 content is increased. The nanocomposites manufactured by the two-step method have better mechanical properties than that made by a one-step method. HIPS/nano-TiO2 nanocomposites are also non-Newtonian and pseudoplastic fluids. (C) 2002 Wiley Periodicals, Inc.
引用
收藏
页码:381 / 385
页数:5
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