Study of high-temperature oxygen states on the silver surface by XPS and UPS

被引：31

作者：

Boronin, AI

Koscheev, SV

Malakhov, VF

Zhidomirov, GM

机构：

[1] Federal Scientific Center, Boreskov Inst. of Catalysis SB RAS

来源：

CATALYSIS LETTERS | 1997年 / 47卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

X-ray photoelectron spectroscopy (XPS); ultraviolet photoelectron spectroscopy (UPS); oxygen states; silver surface; partial oxidation;

D O I：

10.1023/A:1019080232199

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

XPS and UPS methods have been used to study the nature of the oxygen states on silver. Three oxygen states with high E-b(O1s) = 530.5 eV(O-epox), 530.9 eV(O-beta), 532.0eV(O-res) can be reliably attributed to different adsorbed species of quasimolecular oxygen. These states are characterized by an unusually high thermostability(T > 800 K) and a subsurface location.

引用

页码：111 / 117

页数：7

共 37 条

[31] SCF-XALPHA-SW MODEL CALCULATIONS FOR METAL CLUSTERS OF NICKEL, COPPER, AND SILVER AND FOR OXYGEN CHEMISORPTION ON THESE METALS [J].