An organoplatinum molecular hexagon that crystallizes in a hexagonal array

被引：13

作者：

Rashidi, M ^{[1
]}

Jennings, MC ^{[1
]}

Puddephatt, RJ ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

CRYSTENGCOMM | 2003年

关键词：

D O I：

10.1039/b212734b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [PtMe(dppa)(PPh2O)], dppa = Ph2PNHPPh2, which contains chelating dppa and P-bonded diphenylphosphinito ligands, is formed as an insoluble complex on hydrolysis of [PtMe2(dppa)] or by reaction of [PtMe2(dppa)] with Ph2PH(=O); the complex undergoes self-assembly by intermolecular hydrogen bonding NH...OP to form molecular hexagons, that further pack with a hexagonal motif in the crystal lattice.

引用

页码：65 / 66

页数：2

共 23 条

[1]

Atwood J. L., 1996, Comprehensive Supramolecular Chemistry, V6

[2] Organic-organometallic crystal synthesis .1. Hosting paramagnetic [(eta(6)-arene)(2)Cr](+) (arene equals benzene, toluene) in organic anion frameworks via O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds [J].

Braga, D ;

Costa, AL ;

Grepioni, F ;

Scaccianoce, L ;

Tagliavini, E .

ORGANOMETALLICS, 1997, 16 (10) :2070-2079

[3] Design of organometallic molecular and ionic materials [J].

Braga, D ;

Maini, L ;

Polito, M ;

Scaccianoce, L ;

Cojazzi, G ;

Grepioni, F .

COORDINATION CHEMISTRY REVIEWS, 2001, 216 :225-248

[4]

BROWN CL, 1998, FISH DIS DISORDERS, V2, P1

[5] PLATINUM(II) COORDINATION CHEMISTRY OF BIS(DIPHENYLPHOSPHINO)AMINE [J].

BROWNING, CS ;

FARRAR, DH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (04) :521-530

[6] Dinuclear organoplatinum(II)-methyldiphenylphosphine complexes of nicotinic acid [J].

Crisp, MG ;

Pyke, SM ;

Rendina, LM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 607 (1-2) :222-226

[7] Supramolecular motifs: Concerted multiple phenyl embraces between Ph(4)P(+) cations are attractive and ubiquitous [J].

Dance, I ;

Scudder, M .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (05) :481-486

[8] ENCODING AND DECODING HYDROGEN-BOND PATTERNS OF ORGANIC-COMPOUNDS [J].

ETTER, MC .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) :120-126

[9] Self-assembly of an organometallic side-by-side double helix [J].

Fraser, CSA ;

Eisler, DJ ;

Jennings, MC ;

Puddephatt, RJ .

CHEMICAL COMMUNICATIONS, 2002, (11) :1224-1225

[10] An organometallic polyrotaxane and a new type of polyrotaxane architecture [J].

Fraser, CSA ;

Jennings, MC ;

Puddephatt, RJ .

CHEMICAL COMMUNICATIONS, 2001, (14) :1310-1311

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