An organoplatinum molecular hexagon that crystallizes in a hexagonal array

被引：13

作者：

Rashidi, M ^{[1
]}

Jennings, MC ^{[1
]}

Puddephatt, RJ ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

CRYSTENGCOMM | 2003年

关键词：

D O I：

10.1039/b212734b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complex [PtMe(dppa)(PPh2O)], dppa = Ph2PNHPPh2, which contains chelating dppa and P-bonded diphenylphosphinito ligands, is formed as an insoluble complex on hydrolysis of [PtMe2(dppa)] or by reaction of [PtMe2(dppa)] with Ph2PH(=O); the complex undergoes self-assembly by intermolecular hydrogen bonding NH...OP to form molecular hexagons, that further pack with a hexagonal motif in the crystal lattice.

引用

页码：65 / 66

页数：2

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