Allylic Ethers as Educts for Suzuki-Miyaura Couplings in Water at Room Temperature

被引：108

作者：

Nishikata, Takashi ^{[1
]}

Lipshutz, Bruce H. ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 34期

关键词：

COMPLEX-CATALYZED ALLYLATION; CROSS-COUPLINGS; BORONIC ACIDS; ARYL; ALCOHOLS; ACETATES; HALIDES; BONDS; FUNCTIONALIZATION; DEALLYLATION;

D O I：

10.1021/ja905082c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first examples of Suzuki-Miyaura couplings of allylic ethers are reported. These can be done riot only under very mild room-temperature conditions but also in water as the only medium. The process is made possible by micellar catalysis using the designer surfactant PTS.

引用

页码：12103 / +

页数：5

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