The Baylis-Hillman reaction under high pressure induced by water-freezing

被引：48

作者：

Hayashi, Y ^{[1
]}

Okada, K ^{[1
]}

Ashimine, I ^{[1
]}

Shoji, M ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Engn, Dept Ind Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 48期

关键词：

Baylis-Hillman reaction; high-pressure; water-freezing;

D O I：

10.1016/S0040-4039(02)02160-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

High pressure (about 200 MPa), which was realized by freezing water in a sealed autoclave, has been successfully applied to the Baylis-Hillman reaction, in which an efficient rate enhancement was observed. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：8683 / 8686

页数：4

共 31 条

[1] Superior amine catalysts for the Baylis-Hillman reaction: the use of DBU and its implications [J].

Aggarwal, VK ;

Mereu, A .

CHEMICAL COMMUNICATIONS, 1999, (22) :2311-2312

[2] First-examples of metal and ligand accelerated catalysis of the Baylis-Hillman reaction [J].

Aggarwal, VK ;

Tarver, GJ ;

McCague, R .

CHEMICAL COMMUNICATIONS, 1996, (24) :2713-2714

[3] Metal- and ligand-accelerated catalysis of the Baylis-Hillman reaction [J].

Aggarwal, VK ;

Mereu, A ;

Tarver, GJ ;

McCague, R .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (21) :7183-7189

[4] Piperonal as electrophile in the Baylis-Hillman reaction.: A synthesis of hydroxy-β-piperonyl-γ-butyrolactone derivative [J].

Almeida, WP ;

Coelho, F .

TETRAHEDRON LETTERS, 1998, 39 (47) :8609-8612

[5] RATE ENHANCEMENT EFFECTS IN THE DABCO CATALYZED SYNTHESIS OF HYDROXYALKENOATE ESTERS [J].

AMEER, F ;

DREWES, SE ;

FREESE, S ;

KAYE, PT .

SYNTHETIC COMMUNICATIONS, 1988, 18 (05) :495-500

[6] The Baylis-Hillman reaction: A novel carbon-carbon bond forming reaction [J].

Basavaiah, D ;

Rao, PD ;

Hyma, RS .

TETRAHEDRON, 1996, 52 (24) :8001-8062

[7] DABCO CATALYZED DIMERIZATION OF ALPHA,BETA-UNSATURATED KETONES AND NITRILES [J].

BASAVAIAH, D ;

GOWRISWARI, VVL ;

BHARATHI, TK .

TETRAHEDRON LETTERS, 1987, 28 (39) :4591-4592

[8]

Ciganek E., 1997, ORG REACTIONS, V51, P201

[9]

Ciobanu M, 1997, LIEBIGS ANN-RECL, P623

[10] SYNTHETIC POTENTIAL OF THE TERTIARY-AMINE-CATALYSED REACTION OF ACTIVATED VINYL CARBANIONS WITH ALDEHYDES [J].

DREWES, SE ;

ROOS, GHP .

TETRAHEDRON, 1988, 44 (15) :4653-4670

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