Oligomeric and polymeric systems with a cross-conjugated π-framework

被引：318

作者：

Gholami, Mojtaba ^{[1
]}

Tykwinski, Rik R. ^{[1
]}

机构：

[1] Univ Alberta, Dept Chem, Edmonton, AB T6G 2G2, Canada

来源：

CHEMICAL REVIEWS | 2006年 / 106卷 / 12期

关键词：

D O I：

10.1021/cr0505573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cross-conjugated molecules are molecules with "three unsaturated groups, two of which although conjugated to a third unsaturated center are not conjugated to each other". This review focuses on the synthesis and study of oligomeric and polymeric systems in which cross conjugation occurs by virtue of an exocyclic methylene, alkylidene or vinylidene group(s) present within the structure. Specifically, emphasis is on acyclic cross-conjugated systems, cyclic cross-conjugated systems and expanded radialenes.

引用

页码：4997 / 5027

页数：31

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