Recent advances and trends in capillary electrophoresis of inorganic ions

被引:63
作者
Timerbaev, AR [1 ]
机构
[1] Russian Acad Sci, Vernadsky Inst Geochem & Analyt Chem, Moscow 117975, Russia
关键词
capillary electrophoresis; inorganic anions; metal complexes; metal ions; organometallics; review;
D O I
10.1002/elps.200290008
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Capillary electrophoresis (CE) continues its invasion into the domain of inorganic analysis. This review summarizes the progress and significant developments of CE of inorganic ions over the first two years of the new century. As manifested by the substantial number of published articles, this field is still witnessing a growing activity of many separation scientists. To provide an in-depth treatment of fundamental and methodological aspects of inorganic ion analysis by CE, an extensive fraction of the relevant literature is covered whereas only most innovative application reports are briefly considered. Most of the recent advancements have focused on CE system modernization designed to improve a limited detection sensitivity, which still remains a major obstacle to overcome in order to ensure the method's wider practical acceptance. Attention is also given to how and in which directions the future research could be performed to implement CE in routine inorganic analysis.
引用
收藏
页码:3884 / 3906
页数:23
相关论文
共 306 条
[1]   Separation of metalloporphyrins by capillary electrophoresis with UV detection and inductively coupled plasma mass spectrometric detection [J].
Ackley, KL ;
Day, JA ;
Caruso, JA .
JOURNAL OF CHROMATOGRAPHY A, 2000, 888 (1-2) :293-298
[2]   Speciation studies by capillary electrophoresis - distribution of rhodium(III) complexed forms in acidic media [J].
Aleksenko, SS ;
Gumenyuk, AP ;
Mushtakova, SP ;
Timerbaev, AR .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 2001, 370 (07) :865-871
[3]  
Alonso MCB, 2000, ANAL CHIM ACTA, V416, P21, DOI 10.1016/S0003-2670(00)00865-5
[4]   Comparison of two CE-ICP-MS interfaces based on microflow nebulizers:: application to cadmium speciation in metallothioneins using quadrupole and double focusing mass analyzers [J].
Alvarez-Llamas, G ;
de la Campa, MRF ;
Sánchez, MLF ;
Sanz-Medel, A .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2002, 17 (07) :655-661
[5]   Effect of second-sphere coordination 9. Partial inclusion of pentaammineruthenium(II) and pentacyanoferrate(II) complexes with nitrogen heterocycles into a cyclodextrin cavity [J].
Ando, I ;
Ujimoto, K ;
Kurihara, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2001, 74 (04) :717-721
[6]  
Andrighetto P, 2000, ELECTROPHORESIS, V21, P619, DOI 10.1002/(SICI)1522-2683(20000201)21:3<619::AID-ELPS619>3.0.CO
[7]  
2-Y
[8]  
Andrighetto P, 2000, ELECTROPHORESIS, V21, P2384, DOI 10.1002/1522-2683(20000701)21:12<2384::AID-ELPS2384>3.0.CO
[9]  
2-Z
[10]   Injury symptoms and releasing rates of inorganic ions from pine needles as indicators of atmospheric pollution in the Canary Islands forests [J].
Arhoun, M ;
Barreno, E ;
Fos, S ;
Torres-Lapasió, JR ;
Ramis-Ramos, G .
WATER AIR AND SOIL POLLUTION, 2000, 117 (1-4) :105-122