Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA complexes [(C5R5)RuCl(PTA)2] (R = H, Me; PTA=1,3,5-triaza-7-phosphaadamantane)

被引：154

作者：

Akbayeva, DN

Gonsalvi, L

Oberhauser, W

Peruzzini, M

Vizza, F

Brüggeller, P

Romerosa, A

Sava, G

Bergamo, A

机构：

[1] CNR, ICCOM, Ist Chim Composti Organomet, I-50132 Florence, Italy

[2] Univ Innsbruck, Inst Allgemeine Anorgan & Theoret Chem, A-6020 Innsbruck, Austria

[3] Univ Almeria, Area Quim Inorgan, Almeria 04071, Spain

[4] Callerio Fdn Onlus, I-34127 Trieste, Italy

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 02期

关键词：

D O I：

10.1039/b210102e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new water soluble ruthenium complexes [(C5R5) RuCl(PTA)(2)] (R = H, Me; PTA = 1,3,5- triaza-7-phosphaadamantane) were synthesised and characterised. Their evaluation as regioselective catalysts for hydrogenation of unsaturated ketones in aqueous biphasic conditions and as cytotoxic agents towards the TS/A adenocarcinoma cell line is briefly presented.

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页码：264 / 265

页数：2

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