Surface "Click" Chemistry on Brominated Plasma Polymer Thin Films

被引：41

作者：

Chen, Rodney T. ^{[1
]}

Muir, Benjamin W. ^{[1
]}

Such, Georgina K. ^{[2
]}

Postma, Almar ^{[1
]}

Evans, Richard A. ^{[1
]}

Pereira, Suzanne M. ^{[1
]}

McLean, Keith M. ^{[1
]}

Caruso, Frank ^{[2
]}

机构：

[1] CSIRO Mol & Hlth Technol, Clayton, Vic 3168, Australia

[2] Univ Melbourne, Dept Chem & Biomol Engn, Ctr Nanosci & Nanotechnol, Parkville, Vic 3010, Australia

来源：

LANGMUIR | 2010年 / 26卷 / 05期

基金：

澳大利亚研究理事会;

关键词：

MONOTYPE FUNCTIONAL-GROUPS; CHEMICAL-VAPOR-DEPOSITION; SELF-ASSEMBLED MONOLAYERS; TERMINAL ALKYNES; MULTILAYER FILMS; SOLID-SURFACES; AZIDE; CYCLOADDITION; IMMOBILIZATION; COPOLYMERS;

D O I：

10.1021/la9031688

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A brominated plasma polymer (BrPP) thin film was fabricated on a variety of substrate surfaces (silicon wafers, glass, gold, and polymers) via the radio frequency glow discharge of 1-bromopropane. This BrPP thin film was highly adherent and stable and was found to be a useful platform for secondary reactions, leading to surfaces with specific chemical functionalities. Following nucleophilic exchange, an azide-functionalized PP thin film was prepared that was reactive toward two different alkynes via the copper-catalyzed azide-alkyne cycloaddition (CuAAC) reaction, a paradigm of "click" chemistry. "Click" microcontact printing (mu CP) of a fluorescent alkyne was also successfully carried out. demonstrating the versatility and functionality of this new class of reactive thin film plasma polymer coatings.

引用

页码：3388 / 3393

页数：6

共 48 条

[1]

Briggs D, 1992, HIGH RESOLUTION XPS, P277

[2] Spin-on end-functional diblock copolymers for quantitative DNA immobilization [J].

Chen, Lu ;

Rengifo, Henan R. ;

Grigoras, Cristian ;

Li, Xiaoxu ;

Li, Zengmin ;

Ju, Jingyue ;

Koberstein, Jeffrey T. .

BIOMACROMOLECULES, 2008, 9 (09) :2345-2352

[3] Biointerface science [J].

Chilkoti, A ;

Hubbell, JA .

MRS BULLETIN, 2005, 30 (03) :175-176

[4] Clicking functionality onto electrode surfaces [J].

Collman, JP ;

Devaraj, NK ;

Chidsey, CED .

LANGMUIR, 2004, 20 (04) :1051-1053

[5] Preparation of biological labels with acetylenic linker arms [J].

Crisp, GT ;

Gore, J .

TETRAHEDRON, 1997, 53 (04) :1505-1522

[6] Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].

Decher, G .

SCIENCE, 1997, 277 (5330) :1232-1237

[7] Copper catalyzed azide-alkyne cycloadditions on solid surfaces: Applications and future directions [J].

Devaraj, Neal K. ;

Collman, James P. .

QSAR & COMBINATORIAL SCIENCE, 2007, 26 (11-12) :1253-1260

[8] Comparative study of silanisation reactions for the biofunctionalisation of Ti-surfaces [J].

Dubruel, P. ;

Vanderleyden, E. ;

Bergada, M. ;

De Paepe, I. ;

Chen, H. ;

Kuypers, S. ;

Luyten, J. ;

Schrooten, J. ;

Van Hoorebeke, L. ;

Schacht, E. .

SURFACE SCIENCE, 2006, 600 (12) :2562-2571

[9] The rise of azide-alkyne 1,3-dipolar 'click' cycloaddition and its application to polymer science and surface modification [J].

Evans, Richard A. .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2007, 60 (06) :384-395

[10] Modification of polymer surfaces by click chemistry [J].

Fleischmann, Sven ;

Hinrichs, Karsten ;

Oertel, Ulrich ;

Reichelt, Senta ;

Eichhorn, Klaus-Jochen ;

Voit, Brigitte .

MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (12-13) :1177-1185

← 1 2 3 4 5 →