Band gap engineering of poly(p-phenyleneethynylene)s:: Cross-conjugated PPE-PPV hybrids

被引:88
作者
Wilson, JN
Windscheif, PM
Evans, U
Myrick, ML
Bunz, UHF [1 ]
机构
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
[2] Hirsch Apotheke von 1836, D-53498 Bad Breising, Germany
关键词
D O I
10.1021/ma025616i
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Bazan's oligomer concept to allow the synthesis of the hitherto unknown cross-conjugated PPV-PPE copolymers. Since myriads of ketones and aldehydes are commercially available or easily made, their reaction with bodes for the generation of libraries of distyrylbenzenes. These monomers can be used in the synthesis of diversets of cross-conjugate PPE-PPV derivatives with fine-tuned optical/electronic properties.
引用
收藏
页码:8681 / 8683
页数:3
相关论文
共 37 条
[1]   Alkyne metathesis with simple catalyst systems: Efficient synthesis of conjugated polymers containing vinyl groups in main or side chain [J].
Brizius, G ;
Pschirer, NG ;
Steffen, W ;
Stitzer, K ;
zur Loye, HC ;
Bunz, UHF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (50) :12435-12440
[2]   Poly(p-phenyleneethynylene)s by alkyne metathesis [J].
Bunz, UHF .
ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (12) :998-1010
[3]   Poly(aryleneethynylene)s: Syntheses, properties, structures, and applications [J].
Bunz, UHF .
CHEMICAL REVIEWS, 2000, 100 (04) :1605-1644
[4]   A simple orthogonal approach to poly(phenylenevinylene) dendrimers [J].
Deb, SK ;
Maddux, TM ;
Yu, LP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (38) :9079-9080
[5]   Side chain effects in hybrid PPV/PPE polymers [J].
Egbe, DAM ;
Roll, CP ;
Birckner, E ;
Grummt, UW ;
Stockmann, R ;
Klemm, E .
MACROMOLECULES, 2002, 35 (10) :3825-3837
[6]  
Egbe DAM, 2001, MACROMOL CHEM PHYSIC, V202, P2712, DOI 10.1002/1521-3935(20010901)202:13<2712::AID-MACP2712>3.0.CO
[7]  
2-G
[8]   Spectroelectrochemical study of the oxidative doping of polydialkylphenyleneethynylene using iterative target transformation factor analysis [J].
Evans, U ;
Soyemi, O ;
Doescher, MS ;
Bunz, UHF ;
Kloppenburg, L ;
Myrick, ML .
ANALYST, 2001, 126 (04) :508-512
[9]   Evidence of aggregate formation for 2,5-dialkylpoly(p-phenyleneethynylenes) in solution and thin films [J].
Halkyard, CE ;
Rampey, ME ;
Kloppenburg, L ;
Studer-Martinez, SL ;
Bunz, UHF .
MACROMOLECULES, 1998, 31 (25) :8655-8659
[10]  
Hoffmann R, 2001, ANGEW CHEM INT EDIT, V40, P3337, DOI 10.1002/1521-3773(20010917)40:18<3337::AID-ANIE3337>3.0.CO