Diverse synthesis of novel bisterpyridines via Suzuki-type cross-coupling

被引：79

作者：

Han, Fu She

Higuchi, Masayoshi

Kurth, Dirk G.

机构：

[1] Natl Inst Mat Sci, Organ Nanomat Ctr, Funct Modules Grp, Tsukuba, Ibaraki 3050044, Japan

[2] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 04期

关键词：

2,2'/6',2''-TERPYRIDINE; POLYMERS; LIGANDS; COMPLEX; STATE;

D O I：

10.1021/ol062788h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new protocol is presented for the synthesis of novel bisterpyridine derivatives using palladium-catalyzed Miyaura- and Suzuki-type cross-couplings as the key reactions. This protocol is quick, efficient, mild, and broadly applicable for the construction of versatile bisterpyridines by symmetric and unsymmetric introduction of various substituents in the pyridine rings as well as by tuning the spacers for bridging the two terpyridine moieties.

引用

收藏

页码：559 / 562

页数：4

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