Direct methanol fuel cells using thermally catalysed Ti mesh

被引:23
作者
Lim, C [1 ]
Scott, K [1 ]
Allen, RG [1 ]
Roy, S [1 ]
机构
[1] Univ Newcastle Upon Tyne, Dept Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
基金
英国工程与自然科学研究理事会;
关键词
catalyst; direct methanol fuel cell; mesh; Pt-Ru; thermal decomposition;
D O I
10.1023/B:JACH.0000040497.03256.36
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Characterisation of a direct methanol fuel cell using an anode fabricated by thermal decomposition from Pt-Ru chloro-complex on Ti mesh is described. The polarisation characteristic of the resultant membrane electrode assembly is compared with that of a conventional MEA with an anode, consisting of a catalyst layer, a microporous layer and a wet-proof-treated carbon paper. Electrode characterisation was carried out using XRD, SEM and EDX analyses. In 1 M methanol solution, the MEA with the catalysed Ti mesh anode gave a power performance comparable with that of the conventional anode at 90degreesC. However, in 0.5 M methanol solution the former showed much higher power density than the latter, indicating high utilisation of methanol fuel.
引用
收藏
页码:929 / 933
页数:5
相关论文
共 12 条
[1]   Formation of carbon-supported PtM alloys for low temperature fuel cells: a review [J].
Antolini, E .
MATERIALS CHEMISTRY AND PHYSICS, 2003, 78 (03) :563-573
[2]   Carbon dioxide evolution patterns in direct methanol fuel cells [J].
Argyropoulos, P ;
Scott, K ;
Taama, WM .
ELECTROCHIMICA ACTA, 1999, 44 (20) :3575-3584
[3]   Analysis of the electrochemical characteristics of a direct methanol fuel cell based on a Pt-Ru/C anode catalyst [J].
Arico, AS ;
Creti, P ;
Kim, H ;
Mantegna, R ;
Giordano, N ;
Antonucci, V .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (12) :3950-3959
[4]  
BROWN CJ, 1994, J APPL ELECTROCHEM, V24, P95
[5]   Improvement in methanol oxidation in a centrifugal field [J].
Cheng, H ;
Scott, K .
JOURNAL OF POWER SOURCES, 2003, 123 (02) :137-150
[6]   Electrocatalysis in direct methanol fuel cells: in-situ probing of PtRu anode catalyst surfaces [J].
Dinh, HN ;
Ren, XM ;
Garzon, FH ;
Zelenay, P ;
Gottesfeld, S .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2000, 491 (1-2) :222-233
[7]   Electro-oxidation of hydrogen with carbon monoxide on Pt/Ru-based ternary catalysts [J].
He, CZ ;
Kunz, HR ;
Fenton, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (08) :A1017-A1024
[8]   Extended area electrodes based on stacked expanded titanium meshes [J].
Lipp, L ;
Pletcher, D .
ELECTROCHIMICA ACTA, 1997, 42 (07) :1101-1111
[10]   A liquid-feed solid polymer electrolyte direct methanol fuel cell operating at near-ambient conditions [J].
Shukla, AK ;
Christensen, PA ;
Dickinson, AJ ;
Hamnett, A .
JOURNAL OF POWER SOURCES, 1998, 76 (01) :54-59