Excess molar enthalpies of (2,2,4-trimethylpentane, or 1-heptene, or 1-hexene, or toluene plus methyl 1,1-dimethylethyl ether) and of (1-heptene, or 1-hexene, or toluene plus 1,1-dimethylpropyl ether) at the temperatures 298.15 K and 308.15 K

被引：18

作者：

Letcher, TM ^{[1
]}

Domanska, U ^{[1
]}

机构：

[1] WARSAW UNIV TECHNOL,DEPT CHEM,PL-00664 WARSAW,POLAND

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1997年 / 29卷 / 07期

关键词：

excess enthalpy; MTBE; MTAE; molecular interactions; Prigogine-Flory-Patterson model; liquid mixtures;

D O I：

10.1006/jcht.1997.0198

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Flow-microcalorimetric measurements of excess molar enthalpies H-m(E) at the temperatures 298.15 K and 308.15 K are reported for {x(CH3)(3)CCH2CH(CH3)(2), or CH3(CH2)(4)CH=CH2, or CH3(CH2)(3)CH=CH2, or C6H5CH3 + (1 - x)CH3OC(CH3)(3)} and {xCH(3)(CH2)(4)CH=CH2, or CH3(CH2)(3)CH=CH2, or C6H5CH3 + (1 - x)CH3OC(CH3)(2)C2H5}. The results are discussed in terms of the NRTL, UNIQUAC and Prigogine-Flory-Patterson (PFP) models. (C) 1997 Academic Press Limited.

引用

页码：721 / 730

页数：10

共 24 条

[1] THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES [J].