Efficient regio- and diastereo-controlled synthesis of 1,1′- and 1,1′,2,2′-functionalised ferrocenes and the formation of 2-oxa[3]ferrocenophanes

被引:29
作者
Carroll, MA
White, AJP
Widdowson, DA [1 ]
Williams, DJ
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[2] Univ London Imperial Coll Sci Technol & Med, Dept Chem, Chem Crystallog Lab, London SW7 2AY, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 2000年 / 10期
关键词
D O I
10.1039/b000833h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A synthesis of a C-2 symmetric 1,1',2,2'-tetrasubstituted ferrocene system is described. The route involves the reduction of ferrocenyl carbonyl compounds which give access to a range of alcohols, alkenes, alkanes, ethers and 2-oxa[3]ferrocenophanes depending on the precise conditions used.
引用
收藏
页码:1551 / 1557
页数:7
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