Boron-bridged poly(ferrocenylene)s as promising materials for nanoscale molecular wires

被引：42

作者：

Heilmann, Julia B.

Qin, Yang

Jaekle, Frieder

Lerner, Hans-Wolfram

Wagner, Matthias

机构：

[1] Rutgers State Univ, Dept Chem, Newark, NJ 07102 USA

[2] Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany

来源：

INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 15期

基金：

美国国家科学基金会;

关键词：

ferrocene; boron; organoborane; polymer;

D O I：

10.1016/j.ica.2006.05.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

The ferrocene-containing polymer [-fc-B(Br)-](n) (6) with an average chain length of ca. 20 repeat units (n = 20) is readily accessible from fc(BBr2)(2) and HSiEt3 [fc = (C5H4)(2)Fe] via a novel polycondensation reaction. Treatment of 6 with excess THF yields the highly soluble alkoxy-substituted derivative [-fc-B(O(CH2)(4)Br)-](n) (10; n = 20). (c) 2006 Elsevier B.V. All rights reserved.

引用

收藏

页码：4802 / 4806

页数：5

相关论文

共 30 条

[1]

ABDELAZIZ AS, 2003, MACROMOLECULES CONTA, V1

[2]

ARCHER RD, 2001, INORGANIC ORGANOMETA

[3]

DERIVATIVES OF DICYCLOPENTADIENYLIRON [J].

ARIMOTO, FS ;

HAVEN, AC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (23) :6295-6297

[4]

ASO C, 1969, MAKROMOLEKUL CHEM, V124, P232

[5]

Synthesis, electronic structure, and novel reactivity of strained, boron-bridged [1]ferrocenophanes [J].

Berenbaum, A ;

Braunschweig, H ;

Dirk, R ;

Englert, U ;

Green, JC ;

Jäkle, F ;

Lough, AJ ;

Manners, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (24) :5765-5774

[6]

Incorporation of a first row element into the bridge of a strained metallocenophane: Synthesis of a boron-bridged [1]ferrocenophane [J].

Braunschweig, H ;

Dirk, R ;

Muller, M ;

Nguyen, P ;

Resendes, R ;

Gates, DP ;

Manners, I .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (21) :2338-2340

[7]

SYNTHESIS OF POLY(ORGANOBORON HALIDE)S BY HYDROBORATION POLYMERIZATION BETWEEN DIENE AND MONOBROMOBORANE [J].

CHUJO, Y ;

TAKIZAWA, N ;

SAKURAI, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (02) :227-228

[8]

Unsaturated polymers containing boron and thiophene units in the backbone [J].

Corriu, RJP ;

Deforth, T ;

Douglas, WE ;

Guerrero, G ;

Siebert, WS .

CHEMICAL COMMUNICATIONS, 1998, (09) :963-964

[9]

Mesitylcopper: Tetrameric and pentameric [J].

Eriksson, H ;

Hakansson, M .

ORGANOMETALLICS, 1997, 16 (20) :4243-4244

[10]

A NEW CLASS OF AMPEROMETRIC BIOSENSOR INCORPORATING A POLYMERIC ELECTRON-TRANSFER MEDIATOR [J].

HALE, PD ;

INAGAKI, T ;

KARAN, HI ;

OKAMOTO, Y ;

SKOTHEIM, TA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (09) :3482-3484