Assembly of hybrid synthetic capsules

被引:41
作者
Ajami, Dariush
Schramm, Michael P.
Volonterio, Alessandro
Rebek, Julius, Jr.
机构
[1] Scripps Res Inst, Skaggs Inst Chem Biol, La Jolla, CA 92037 USA
[2] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
关键词
host-guest systems; molecular recognition; reversible encapsulation; self-assembly;
D O I
10.1002/anie.200603421
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Different, yet compatible: A hybrid capsule is formed through hydrogen bonding between two different subunits, each of which is capable of self-assembly into homodimeric capsules. The hybrid forms in response to a guest that fills its space properly. Formation of the molecular capsule (see picture) is supported by 1H NMR spectroscopy experiments. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:242 / 244
页数:3
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