Photodimerization of acenaphthylene within a nanocapsule: excited state lifetime dependent dimer selectivity

被引：52

作者：

Kaanumalle, Lakshmi S. ^{[1
]}

Ramamurthy, V. ^{[1
]}

机构：

[1] Univ Miami, Dept Chem, Coral Gables, FL 33146 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 10期

关键词：

D O I：

10.1039/b615937k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct excitation of acenaphthylene molecules included in a syn fashion within the octa acid nanocapsule dimerizes quantitatively to a syn dimer, and upon triplet sensitization, yields both syn and anti dimers probably by reacting within and outside the capsule.

引用

页码：1062 / 1064

页数：3