Plasma-assisted molecular beam epitaxy of high quality In2O3(001) thin films on Y-stabilized ZrO2(001) using In as an auto surfactant

被引:49
作者
Bierwagen, Oliver [1 ]
White, Mark E. [1 ]
Tsai, Min-Ying [2 ]
Speck, James S. [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Elect & Comp Engn, Santa Barbara, CA 93106 USA
关键词
free energy; indium compounds; molecular beam epitaxial growth; plasma materials processing; semiconductor growth; semiconductor materials; semiconductor thin films; surface energy; surface roughness; surfactants; yttrium compounds; zirconium compounds; GAN SURFACE; TIN OXIDE; GROWTH; DEPOSITION; SUBSTRATE; SAPPHIRE; ZIRCONIA; INAS;
D O I
10.1063/1.3276910
中图分类号
O59 [应用物理学];
学科分类号
摘要
The surface roughness of In2O3(001) films is a roadblock to potential semiconductor applications of this material. Using plasma-assisted molecular beam epitaxy we found that In2O3(001) films grow rough by the formation of {111} facets and In2O3(111) films grow smooth without facetting due to the conventionally used (oxygen-rich) conditions. This behavior indicates that the (111) surface is thermodynamically prefered over the (001) surface. We demonstrate that under indium-rich growth conditions these thermodynamics are changed allowing In2O3(001) films to grow smoothly without facetting. Surface indium plays a key role by acting as an auto surfactant that lowers the surface free energy difference between the (001) and the (111) surface.
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页数:3
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