Asymmetric synthesis of chiral α-ferrocenylalkylamines and their use in the preparation of chiral redox-active receptors

被引:41
作者
Laurent, P
Miyaji, H
Collinson, SR
Prokes, I
Moody, CJ
Tucker, JHR
Slawin, AMZ
机构
[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England
[2] Univ St Andrews, Dept Chem, St Andrews KY16 9ST, Fife, Scotland
关键词
D O I
10.1021/ol020162v
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] A new strategy for the asymmetric synthesis of chiral primary alpha-ferrocenylalkylamines has been utilized to generate homochiral redox-active receptors that bind chiral carboxylate anions with moderate enantioselectivity and undergo a redox response to complexation.
引用
收藏
页码:4037 / 4040
页数:4
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