The high-pressure behaviour of 3R-NbS2

被引:6
作者
Ehm, L [1 ]
Knorr, K [1 ]
Depmeier, W [1 ]
机构
[1] Univ Kiel, Inst Geowissensch, D-24098 Kiel, Germany
来源
ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 2002年 / 217卷 / 10期
关键词
D O I
10.1524/zkri.217.10.522.20793
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The high pressure behaviour of 3R-NbS2 has been investigated by angle-dispersive X-ray powder diffraction using diamond anvil cells up to 14 GPa. The compression behaviour of the structure is highly anisotropic. The compressibility perpendicular to the layers is 2.5 times higher than within the layers. The fit of a 3(rd)-order Birch-Mumaghan equation of state gave a volume at zero pressure V-0 = 174(1) Angstrom(3) and a bulk modulus b(0) = 57(1) GPa, with a pressure derivative b' = 8.6(5).
引用
收藏
页码:522 / 524
页数:3
相关论文
共 22 条
[21]   HIGH-PRESSURE INVESTIGATIONS OF MOS2 [J].
WEBB, AW ;
FELDMAN, JL ;
SKELTON, EF ;
TOWLE, LC ;
LIU, CY ;
SPAIN, IL .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1976, 37 (03) :329-335
[22]   INTERCALATION CHEMISTRY AND ENERGY-STORAGE [J].
WHITTINGHAM, MS .
JOURNAL OF SOLID STATE CHEMISTRY, 1979, 29 (03) :303-310