Homochiral tripodal imidazolium receptors: structural and anion-receptor studies

被引:10
作者
Alhashimy, Nameer
Brougham, Dermot J.
Howarth, Joshua
Farrell, Alan
Quilty, Brid
Nolan, Kieran [1 ]
机构
[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland
[2] Dublin City Univ, Natl Inst Cellular Biotechnol, Dublin 9, Ireland
[3] Dublin City Univ, Sch Biotechnol, Dublin 9, Ireland
[4] Dublin City Univ, Natl Ctr Sensor Res, Dublin 9, Ireland
关键词
tripodal imidazolium receptors; homochiral; anion recognition; x-ray; Candida albicans;
D O I
10.1016/j.tetlet.2006.10.143
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Two homochiral tripodal receptors were characterised by X-ray crystallography, the first examples for this class of imidazolium receptor. These receptors were also screened for anion recognition. Both receptors demonstrated selectivity towards chloride and bromide with binding constants as high as 16,000. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:125 / 128
页数:4
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