Metallocene-catalyzed diastereoselective epoxidation of allylic alcohols

被引：18

作者：

Della Sala, G ^{[1
]}

Giordano, L ^{[1
]}

Lattanzi, A ^{[1
]}

Proto, A ^{[1
]}

Scettri, A ^{[1
]}

机构：

[1] Univ Salerno, Dipartimento Chim, I-84081 Baronissi, SA, Italy

来源：

TETRAHEDRON | 2000年 / 56卷 / 22期

关键词：

diastereoselection; epoxidation; titanium and compounds; zirconium and compounds;

D O I：

10.1016/S0040-4020(00)00266-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylic alcohols undergo an efficient process of diastereoselective epoxidation by t-butyl hydroperoxide (TBHP) in n-hexane solution in the presence of catalytic amounts of mono- and bis-cyclopentadienyl titanium(IV) and zirconium(IV) chlorides. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3567 / 3573

页数：7

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