Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks

被引:357
作者
Choi, Hye-Sun [1 ]
Suh, Myunghyun Paik [1 ]
机构
[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea
关键词
adsorption; carbon dioxide capture; macrocyclic complexes; nickel; organic-inorganic hybrid composites; METAL-ORGANIC FRAMEWORK; ZEOLITIC IMIDAZOLATE FRAMEWORKS; SINGLE-CRYSTAL TRANSFORMATIONS; ION-EXCHANGE PROPERTIES; BILAYER OPEN FRAMEWORK; CARBON-DIOXIDE; PALLADIUM NANOPARTICLES; ADSORPTION SELECTIVITY; MACROCYCLIC COMPLEXES; SORPTION PROPERTIES;
D O I
10.1002/anie.200902836
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Keeping limber: Three-dimensional coordination polymers incorporating flexible pillars (see picture, left) exhibit highly selective adsorption of CO2 over N2, H2, and CH4 (see picture, right), thermal stability up to 300 °C, as well as air and water stability, and allow efficient CO2 capture, storage, and sensing. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:6865 / 6869
页数:5
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