共 58 条
Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks
被引:357
作者:
Choi, Hye-Sun
[1
]
Suh, Myunghyun Paik
[1
]
机构:
[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea
关键词:
adsorption;
carbon dioxide capture;
macrocyclic complexes;
nickel;
organic-inorganic hybrid composites;
METAL-ORGANIC FRAMEWORK;
ZEOLITIC IMIDAZOLATE FRAMEWORKS;
SINGLE-CRYSTAL TRANSFORMATIONS;
ION-EXCHANGE PROPERTIES;
BILAYER OPEN FRAMEWORK;
CARBON-DIOXIDE;
PALLADIUM NANOPARTICLES;
ADSORPTION SELECTIVITY;
MACROCYCLIC COMPLEXES;
SORPTION PROPERTIES;
D O I:
10.1002/anie.200902836
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Keeping limber: Three-dimensional coordination polymers incorporating flexible pillars (see picture, left) exhibit highly selective adsorption of CO2 over N2, H2, and CH4 (see picture, right), thermal stability up to 300 °C, as well as air and water stability, and allow efficient CO2 capture, storage, and sensing. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:6865 / 6869
页数:5
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