Characterization of porous carbonaceous materials derived from poly(phenylenebutadiynylene)s

被引：12

作者：

Kijima, Masashi ^{[1
]}

Tanimoto, Hisashi ^{[1
]}

Takakura, Kosuke ^{[1
]}

Fujiya, Dai ^{[1
]}

Ayuta, Yoshiaki ^{[1
]}

Matsuishi, Kiyoto ^{[1
]}

机构：

[1] Univ Tsukuba, Grad Sch Pure & Appl Sci, Inst Mat Sci, Tsukuba, Ibaraki 3058573, Japan

来源：

CARBON | 2007年 / 45卷 / 03期

基金：

日本学术振兴会;

关键词：

D O I：

10.1016/j.carbon.2006.10.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Poly(phenylenebutadiynylene) derivatives (PPBs) were synthesized and carbonized by thermolysis from room temperature to 900 degrees C under flowing argon, affording porous carbonaceous materials in high yields. The nanostructures and the graphitization behavior of the carbonized materials were investigated by XRD, Raman, electron microscopy, and N, adsorption methods. The carbonized material was made up with basic structural units of carbonaceous layers having an average dimension of 2-4 nm and a wide interlayer distance of 0.4 nm. The nano-space was created by organization of the basic structural units, which resulted in microporosity of the material. The carbonized materials were hard to graphitize by heat treatment of higher temperature. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：594 / 601

页数：8

共 33 条

[1] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].

BARRETT, EP ;

JOYNER, LG ;

HALENDA, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380

[2] On the characterization of disordered and heterogeneous carbonaceous materials by Raman spectroscopy [J].

Beyssac, O ;

Goffé, B ;

Petitet, JP ;

Froigneux, E ;

Moreau, M ;

Rouzaud, JN .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2003, 59 (10) :2267-2276

[3] On a theory of the van der Waals adsorption of gases [J].

Brunauer, S ;

Deming, LS ;

Deming, WE ;

Teller, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1940, 62 :1723-1732

[4] PORE-SIZE DISTRIBUTION IN TYPICAL ADSORBENT SYSTEMS [J].

DOLLIMORE, D ;

HEAL, GR .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1970, 33 (04) :508-+

[5] Characterisation of carbonaceous materials derived from polyparaphenylene pyrolyzed at low temperature [J].

Dubois, M ;

Naji, A ;

Buisson, JP ;

Humbert, B ;

Grivei, E ;

Billaud, D .

CARBON, 2000, 38 (09) :1411-1417

[6] A ONE-STEP PROCESS FOR FABRICATION OF CARBON-CARBON COMPOSITES [J].

ECONOMY, J ;

JUNG, H ;

GOGEVA, T .

CARBON, 1992, 30 (01) :81-85

[7] Pore structures of activated carbon fibers from organometallics/pitch composites by nitrogen adsorption [J].

El-Merraoui, M ;

Tamai, H ;

Yasuda, H ;

Kanata, T ;

Mondori, J ;

Nadai, K ;

Kaneko, K .

CARBON, 1998, 36 (12) :1769-1776

[8] RAMAN STUDIES OF HEAT-TREATED CARBON-BLACKS [J].

GRUBER, T ;

ZERDA, TW ;

GERSPACHER, M .

CARBON, 1994, 32 (07) :1377-1382

[9] OXIDATIVE COUPLING OF ACETYLENES [J].

HAY, AS .

JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (07) :1275-1276

[10] Surface properties of porous carbon obtained from polystyrene sulfonic acid-based organic salts [J].

Hines, D ;

Bagreev, A ;

Bandosz, TJ .

LANGMUIR, 2004, 20 (08) :3388-3397

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