A molecularly imprinted polymer rod as nicotine selective affinity media prepared with 2-(trifluoromethyl)acrylic acid

被引：49

作者：

Matsui, J ^{[1
]}

Takeuchi, T ^{[1
]}

机构：

[1] HIROSHIMA CITY UNIV,FAC INFORMAT SCI,LAB SYNTHET BIOCHEM,ASAMINAMI KU,HIROSHIMA 73131,JAPAN

来源：

ANALYTICAL COMMUNICATIONS | 1997年 / 34卷 / 07期

关键词：

D O I：

10.1039/a703189k

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In situ molecular imprinting was performed using 2-(trifluoromethyl)acrylic acid (TFMAA) as a functional monomer to prepare rod-type affinity media for nicotine in liquid chromatography, The capacity factor of nicotine was 28.4 using an eluent of acetonitrile-acetic acid (98:2, v/v), while a polymer rod prepared by a conventional in situ method, employing methacrylic acid as functional monomer, resulted in a capacity factor of 2.4, showing that TFMAA is useful in in situ molecular imprinting for developing high-affinity chromatographic media.

引用

页码：199 / 200

页数：2