Preparation and characterization, of single-crystalline bismuth nanowires by a low-temperature solvothermal process

被引:75
作者
Gao, YH [1 ]
Niu, HL [1 ]
Zeng, C [1 ]
Chen, QW [1 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Struct Res Lab, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0009-2614(02)01680-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Single-crystalline metallic bismuth nanowires have been successfully prepared by a solvothermal process at low temperatures, using aqueous bismuth nitrate [Bi(NO3)(3) . 5H(2)O] and ethylene diamine (H2NCH2CH2NH2) as starting materials. Characterizations have been carried out by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The diameter of the nanowires is about 20-30 nm and lengths range from 0.2 to 2.5 mum. The reduction of bismuth ions (Bi3+) and formation mechanism of nanowire were discussed based on the characteristic of the-reaction system employed. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:141 / 144
页数:4
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