The ionic liquid ethyltri-n-butylphosphonium tosylate as solvent for the acid-catalysed hetero-Michael reaction

被引：32

作者：

Karodia, Nazira ^{[1
]}

Liu, Xihan ^{[1
]}

Ludley, Petra ^{[1
]}

Pletsas, Dirnitrios ^{[1
]}

Stevenson, Grace ^{[1
]}

机构：

[1] Univ Bradford, Sch Life Sci, Bradford BD7 1DP, W Yorkshire, England

来源：

TETRAHEDRON | 2006年 / 62卷 / 48期

关键词：

D O I：

10.1016/j.tet.2006.09.052

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and convenient method for the acid-catalysed Michael addition reactions of alcohols, thiols and amines to methyl vinyl ketone has been developed using the ionic liquid ethyltri-n-butylphosphonium tosylate. The reaction conditions are mild and obviate the need for toxic and expensive Lewis acid catalysts, offering advantages over more commonly used systems. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：11039 / 11043

页数：5

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