Chemical functionalization of graphene

被引：353

作者：

Boukhvalov, D. W. ^{[1
]}

Katsnelson, M. I. ^{[1
]}

机构：

[1] Radboud Univ Nijmegen, Inst Mol & Mat, NL-6525 AJ Nijmegen, Netherlands

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 2009年 / 21卷 / 34期

关键词：

CARBON NANOTUBES; SEMIEMPIRICAL CALCULATIONS; HALF-METALLICITY; ATOMIC-HYDROGEN; CHEMISTRY; NANORIBBON; OXIDATION; STORAGE; LAYER; NANOPARTICLES;

D O I：

10.1088/0953-8984/21/34/344205

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Experimental and theoretical results on chemical functionalization of graphene are reviewed. Using hydrogenated graphene as a model system, general principles of the chemical functionalization are formulated and discussed. It is shown that, as a rule, 100% coverage of graphene by complex functional groups (in contrast with hydrogen and fluorine) is unreachable. A possible destruction of graphene nanoribbons by fluorine is considered. The functionalization of infinite graphene and graphene nanoribbons by oxygen and by hydrofluoric acid is simulated step by step.

引用

页数：12

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