Gold(I)-catalyzed isomerization of allenyl carbinol esters: An efficient access to functionalized 1,3-butadien-2-ol esters

被引：84

作者：

Buzas, Andrea K. ^{[1
]}

Istrate, Florin M. ^{[1
]}

Gagosz, Fabien ^{[1
]}

机构：

[1] Ecole Polytech, CNRS, UMR 7652, Organ Synth Lab, F-91128 Palaiseau, France

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 06期

关键词：

D O I：

10.1021/ol063031t

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A study concerning the gold(I)-catalyzed rearrangement of diversely substituted allenyl carbinol esters into functionalized 1,3-butadien-2-olesters is described. The mild conditions employed allow the efficient, rapid, and stereoselective synthesis of a variety of such compounds via a new 1,3-shift of an ester moiety onto a gold-activated allene.

引用

页码：985 / 988

页数：4

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