Asymmetric synthesis of the A-ring part of ciguatoxin by the strategy based on diastereoselective hydroboration and ring closing metathesis

被引：33

作者：

Fujiwara, K ^{[1
]}

Tanaka, H ^{[1
]}

Murai, A ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Sapporo, Hokkaido 0600810, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 06期

关键词：

D O I：

10.1246/cl.2000.610

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric synthesis of the A-ring part of a marine toxin ciguatoxin (CTX1B) was achieved by the strategy based on ring closing metathesis (RCM), where introduction of the C5 asymmetric center was performed by diastereocontrolled hydroboration of a vinyl ether moiety.

引用

页码：610 / 611

页数：2

共 69 条

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