Preparation of polymer nanocomposites of core-shell structure via surface-initiated atom transfer radical polymerizations

被引:29
作者
Lei, Zhongli [1 ]
Bi, Shuxian [1 ]
机构
[1] Shaanxi Normal Univ, Key Lab Macromol Sci Shaanxi Prov, Sch Chem & Mat Sci, Xian 710062, Peoples R China
关键词
surface-initiated; atom transfer radical polymerization; poly(tert-butyl acrylate); graft polymerization; silica particles;
D O I
10.1016/j.matlet.2006.11.120
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polymer nanocomposites of core-shell structure were prepared by grafting poly(tert-butyl acrylate) (Pt-BA) from SiO2 nanoparticle via the surface-initiated polymerization (SIP) strategy. This new organic inorganic hybrid particle has been extensively characterized by XPS (X-ray Photoelectron Spectroscopy), SEM (Scanning Electron Microscopy), TEM (Transmission Electron Microscopy), and TGA (ThermoGravimetric Analysis). (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:3531 / 3534
页数:4
相关论文
共 29 条
[1]   Surface initiated polymerization from nanoparticle surfaces [J].
Advincula, RC .
JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2003, 24 (3-4) :343-361
[2]   Organic/inorganic hybrids by 'living'/controlled ATRP grafting from layered silicates [J].
Böttcher, H ;
Hallensleben, ML ;
Nuss, S ;
Wurm, H ;
Bauer, J ;
Behrens, P .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (05) :1351-1354
[3]   Synthesis and aqueous solution properties of polyelectrolyte-grafted silica particles prepared by surface-initiated atom transfer radical polymerization [J].
Chen, XY ;
Randall, DP ;
Perruchot, C ;
Watts, JF ;
Patten, TE ;
von Werne, T ;
Armes, SP .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2003, 257 (01) :56-64
[4]   Polymer brushes grafted from clay nanoparticles adsorbed on a planar substrate by free radical surface-initiated polymerization [J].
Fan, XW ;
Xia, CJ ;
Fulghum, T ;
Park, MK ;
Locklin, J ;
Advincula, RC .
LANGMUIR, 2003, 19 (03) :916-923
[5]  
Giannelis EP, 1999, ADV POLYM SCI, V138, P107
[6]   ESCA STUDY OF ORGANOSILICON COMPOUNDS [J].
GRAY, RC ;
CARVER, JC ;
HERCULES, DM .
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1976, 8 (05) :343-357
[7]   Polyaniline: A polymer with many interesting intrinsic redox states [J].
Kang, ET ;
Neoh, KG ;
Tan, KL .
PROGRESS IN POLYMER SCIENCE, 1998, 23 (02) :277-324
[8]   Controlled functionalization of multiwalled carbon nanotubes by in situ atom transfer radical polymerization [J].
Kong, H ;
Gao, C ;
Yan, DY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) :412-413
[9]  
Lahann J, 2001, MACROMOL RAPID COMM, V22, P968
[10]   Synthesis of well-defined polymer brushes grafted onto silica nanoparticles via surface reversible addition-fragmentation chain transfer polymerization [J].
Li, CZ ;
Benicewicz, BC .
MACROMOLECULES, 2005, 38 (14) :5929-5936