共 5 条
CRYSTAL ENGINEERING Towards artificial enzymes
被引:30
作者:
Hupp, Joseph T.
[1
,2
]
机构:
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
关键词:
CHEMISTRY;
CLATHRATE;
VOIDS;
D O I:
10.1038/nchem.678
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Despite knowing that the active centres of many metalloprotein enzymes are iron porphyrin 'haem' complexes, chemists find them difficult to imitate. Now, the assembly of haem-like centres into a crystalline, stable, nanoporous array shows promise for biomimetic catalysis.
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页码:432 / 433
页数:2
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