Intramolecular photocycloaddition of 2-(2-alkenyloxymethyl)naphthalene-1-carbonitriles using glass-made microreactors

被引：36

作者：

Mukae, Hirofumi ^{[1
]}

Maeda, Hajime ^{[1
]}

Nashihara, Satoshi ^{[1
]}

Mizuno, Kazuhiko ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Chem, Naka Ku, Sakai, Osaka 5998531, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2007年 / 80卷 / 06期

关键词：

D O I：

10.1246/bcsj.80.1157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intramolecular [2 + 2] and [2 + 3] photocycloadditions of 2-(2-alkenyloxymethyl)naphthalene-1-carbonitriles and their photocycloreversion using glass-made microreactors were investigated in comparison with photoreactions under conventional batch conditions. Both the efficiency and regioselectivity were improved by use of glass-made microreactors. These results can be explained by thorough absorption of light and outflow of primary product from the reaction system.

引用

页码：1157 / 1161

页数：5

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