Extremely high enantiomer recognition in HPLC separation of racemic 2-(benzylsulfinyl)benzamide using cellulose tris(3,5-dichlorophenylcarbamate) as a chiral stationary phase

被引：60

作者：

Chankvetadze, B

Yamamoto, C

Okamoto, Y ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Tbilisi State Univ, Sch Chem, Mol Recognit & Separat Sci Lab, GE-380028 Tbilisi, Georgia

来源：

CHEMISTRY LETTERS | 2000年 / 10期

关键词：

D O I：

10.1246/cl.2000.1176

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An extremely high enantioselectivity of cellulose tris(3,5-dichlorophenylcarbamate) was found when it was used as a chiral stationary phase (CSP) in high-performance liquid chromatography (HPLC). The enantioseparation factor (alpha = 112) reported in this system for 2-(benzylsulfinyl)benzamide seems to be the highest among many enantiomer-differentiating separations using polysaccharide derivatives as CSPs.

引用

页码：1176 / 1177

页数：2

共 24 条

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