Stille cross-couplings of unactivated secondary alkyl halides using monoorganotin reagents

被引：155

作者：

Powell, DA ^{[1
]}

Maki, T ^{[1
]}

Fu, GC ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 02期

关键词：

D O I：

10.1021/ja0436300

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first catalyst that achieves Stille cross-couplings of secondary (as well as primary) alkyl halides has been developed. The method employs easily handled and inexpensive catalyst components (NiCl2 and 2,2′-bipyridine) and, through the use of monoorganotin reagents, avoids the formation of toxic and difficult-to-remove triorganotin side products. Copyright © 2005 American Chemical Society.

引用

页码：510 / 511

页数：2

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