Recent developments in the synthesis and structure of organosilanols

被引：294

作者：

Chandrasekhar, V ^{[1
]}

Boomishankar, R ^{[1
]}

Nagendran, S ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 12期

关键词：

D O I：

10.1021/cr0306135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The initial observations on the instability of Me2Si(OH) 2 toward self-condensation fueled interest on silanols. Various types of stable silanols came to be known. Specifically, stable molecular compounds containing Si-OH, Si-(OH)2, and Si-(OH) 3 units have been synthesized and structurally characterized. As a result of continuous development, it is now possible by a careful choice of an appropriate silanol and a metal substrate to design and assemble specific metallasiloxanes of interest.

引用

页码：5847 / 5910

页数：64

共 237 条

[81] Synthesis, characterization and reactivity of cis-cis-cis [(C6H5)4Si4O4(OH)4] [J].

Feher, FJ ;

Schwab, JJ ;

Soulivong, D ;

Ziller, JW .

MAIN GROUP CHEMISTRY, 1997, 2 (02) :123-132

[82] SILASESQUIOXANES AS LIGANDS IN INORGANIC AND ORGANOMETALLIC CHEMISTRY [J].

FEHER, FJ ;

BUDZICHOWSKI, TA .

POLYHEDRON, 1995, 14 (22) :3239-3253

[83] Facile and remarkably selective substitution reactions involving framework silicon atoms in silsesquioxane frameworks [J].

Feher, FJ ;

Phillips, SH ;

Ziller, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (14) :3397-3398

[84] New vanadium tris(tert-butoxy)siloxy complexes and their thermolytic conversions to vanadia-silica materials [J].

Fujdala, KL ;

Tilley, TD .

CHEMISTRY OF MATERIALS, 2002, 14 (03) :1376-1384

[85] Boron, aluminum, and gallium silsesquioxane compounds, homogeneous models for group 13 element-containing silicates and zeolites [J].

Gerritsen, G ;

Duchateau, R ;

van Santen, RA ;

Yap, GPA .

ORGANOMETALLICS, 2003, 22 (01) :100-110

[86] Studies in silanol synthesis: internal nucleophiles and steric hindrance [J].

Glekas, A ;

Sieburth, SM .

TETRAHEDRON LETTERS, 2001, 42 (23) :3799-3801

[87] IRIDIUM-SILANOL COMPLEXES FROM DIRECT OXIDATIVE ADDITION OF SILANOLS TO IR(I) - SYNTHESIS AND X-RAY STRUCTURE OF THE METALLOSILANOLATE [(ET(3)P)(2)IR(H)(CL)((SIPR2OLI)-PR-I)](2) [J].

GOIKHMAN, R ;

AIZENBERG, M ;

KRAATZ, HB ;

MILSTEIN, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (21) :5865-5866

[88] Iridium- and rhodium-silanol complexes: Synthesis and reactivity [J].

Goikhman, R ;

Aizenberg, M ;

Shimon, LJW ;

Milstein, D .

ORGANOMETALLICS, 2003, 22 (20) :4020-4024

[89] Transition metal-catalyzed silanone generation [J].

Goikhman, R ;

Aizenberg, M ;

Shimon, LJW ;

Milstein, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (44) :10894-10895

[90] Formation of a tantalum siloxane cage complex in the reaction of (eta(5)-C5Me5)TaMe4 with a silanetriol [J].

Gouzyr, AI ;

Wessel, H ;

Barnes, CE ;

Roesky, HW ;

Teichert, M ;

Uson, I .

INORGANIC CHEMISTRY, 1997, 36 (16) :3392-&

← 4 5 6 7 8 9 10 11 12 13 →