Selective formation of carbon nanotubes over Co-modified beta zeolite by CCVD

被引:32
作者
Ciambelli, P
Sannino, D
Sarno, M
Fonseca, A
Nagy, JB
机构
[1] Univ Salerno, Dept Chem & Food Engn, I-84084 Fisciano, SA, Italy
[2] Fac Univ Notre Dame Paix, Lab RMN, B-5000 Namur, Belgium
关键词
carbon nanotubes; chemical vapor deposition; electron microscopy; X-ray diffraction;
D O I
10.1016/j.carbon.2004.10.027
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Multiwall carbon nanotubes containing carbon-zeolite composite materials have been obtained by ethylene catalytic chemical vapor deposition (CCVD) on Co-modified beta zeolite powder. High carbon selectivity to nanotubes was achieved. The combined physical characterisation through several techniques, such as TEM, HRTEM, SEM, XRD, N-2 adsorption-desorption, allows to determine the geometric characteristics of nanotubes and their dependence of catalyst and synthesis conditions. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:631 / 640
页数:10
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