Polystyrylboronic acid as a reusable polymeric support for oligosaccharide synthesis

被引：31

作者：

Belogi, G ^{[1
]}

Zhu, T ^{[1
]}

Boons, GJ ^{[1
]}

机构：

[1] Univ Georgia, Complex Carbohydrate Res Ctr, Athens, GA 30602 USA

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 36期

关键词：

D O I：

10.1016/S0040-4039(00)01184-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Polystyrylboronic acid is an attractive polymeric support for oligosaccharide synthesis that can easily be prepared in high loading capacity and re-used after a synthetic sequence. Saccharides were loaded by heating in pyridine and released by treatment with a mixture of acetone and water. NIS/TMSOTf mediated glycosidations of thioglycosides gave a quantitative formation of disaccharides. (C) 2000 Published by Elsevier Science Ltd.

引用

页码：6965 / 6968

页数：4

共 29 条

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