The first calibration of an aminiumyl radical ion clock:: why N-cyclopropylanilines may be poor mechanistic probes for single electron transfer

被引：18

作者：

Li, Xiangzhong ^{[1
]}

Grimm, Michelle L. ^{[1
]}

Igarashi, Kazuo ^{[1
]}

Castagnoli, Neal, Jr. ^{[1
]}

Tanko, J. M. ^{[1
]}

机构：

[1] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 25期

关键词：

D O I：

10.1039/b702157g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using direct and indirect electrochemical methods, the rate constant for ring opening of the radical cation generated from N-cyclopropyl-N-methylaniline was found to be 4.1 x 10(4) s(-1).

引用

页码：2648 / 2650

页数：3

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