Novel two-dimensional network constructed from polyoxomolybdate chains linked through copper-organonitrogen coordination polymer chains:: Hydrothermal synthesis and structure of [H2bpy][Cu(4,4′-bpy)]2[HPCuMo11O39]

被引：180

作者：

Lu, Y

Xu, Y

Wang, EB ^{[1
]}

Lü, J

Hu, CW

Xu, L

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

[2] Univ Tokyo, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CRYSTAL GROWTH & DESIGN | 2005年 / 5卷 / 01期

关键词：

D O I：

10.1021/cg0498960

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel compound, [H(2)bpy][Cu(4,4'-bpy)](2)[HPCuMo11O39] (1), has been prepared under mild hydrothermal conditions and has been structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a novel two-dimensional network constructed from the interconnecting of polyoxomolybdate chains, {HPCuMo11O39}(n)(4n-), and transition metal coordination polymer chains, {Cu(4,4'-bpy)}(n)(n+). It is the first example of a two-dimensional structure formed by a polyoxomolybdate chain through the linkage of a transition metal coordination polymer chain.

引用

收藏

页码：257 / 260

页数：4

相关论文

共 29 条

[1] DODECATUNGSTOPHOSPHORIC ACID HEXAHYDRATE, (H5O2+)3(PW12O403-) - TRUE STRUCTURE OF KEGGINS PENTAHYDRATE FROM SINGLE-CRYSTAL X-RAY AND NEUTRON-DIFFRACTION DATA [J].

BROWN, GM ;

NOESPIRLET, MR ;

BUSING, WR ;

LEVY, HA .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1977, 33 (APR15) :1038-1046

[2] Chiral noninterpenetrated (10,3)-a net in the crystal structure of Ag(I) and bisthioether [J].

Bu, XH ;

Chen, W ;

Du, M ;

Biradha, K ;

Wang, WZ ;

Zhang, RH .

INORGANIC CHEMISTRY, 2002, 41 (02) :437-+

[3]

Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO

[4]

2-U

[5] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[6] Hybrid organic-anorganic 1D and 2D frameworks with ε-Keggin polyoxomolybdates as building blocks [J].

Dolbecq, A ;

Mialane, P ;

Lisnard, L ;

Marrot, J ;

Sécheresse, F .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (12) :2914-2920

[7] Crystal structures of [NEt(3)H](5)[XCo(II)W(11)O(39)]center dot 3H(2)O (X=P or As) [J].

Evans, HT ;

Weakley, TJR ;

Jameson, GB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (12) :2537-2540

[8] A NOVEL CHAIN-LIKE HETEROPOLYANION FORMED BY KEGGIN UNITS - SYNTHESIS AND STRUCTURE OF (ET)(8N)[PMNW11O39](N)CENTER-DOT-2NH(2)O [J].

GALANMASCAROS, JR ;

GIMENEZSAIZ, C ;

TRIKI, S ;

GOMEZGARCIA, CJ ;

CORONADO, E ;

OUAHAB, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (13-14) :1460-1462

[9] Composite solids constructed from one-dimensional coordination polymer matrices and molybdenum oxide subunits: Polyoxomolybdate clusters within [{Cu(4,4'-bpy)}(4)Mo8O26] and [{Ni(H2O)(2)(4,4'-bpy)(2)}(2)Mo8O26] and one-dimensional oxide chains in [{Cu(4,4'-bpy)}(4)Mo15O47]center dot 8H(2)O [J].

Hagrman, D ;

Zubieta, C ;

Rose, DJ ;

Zubieta, J ;

Haushalter, RC .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (08) :873-876

[10] Solid state coordination chemistry: two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits [J].

Hagrman, D ;

Sangregorio, C ;

O'Connor, CJ ;

Zubieta, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (22) :3707-3709