Hydrothermal synthesis and characterization of a novel two-dimensional framework materials constructed from the polyoxometalates and coordination groups:: [As8IIIV14IVO42(CO3)][Cu(en)2]3•10H2O

被引：48

作者：

Cui, XB ^{[1
]}

Sun, YQ ^{[1
]}

Yang, GY ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, Coordinat & Hydrothermal Chem Grp, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 03期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; two-dimensional structure; As/V/O polyoxometalates; crystal structure; coordination groups;

D O I：

10.1016/S1387-7003(02)00740-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new compound [(As8V14O42)-V-III-O-IV(CO3)][Cu(en)2]3 . 10H(2)O (1) has been synthesized from V2O5,As2O3CuCl2 . 2H(2)O, en and H2C2O4 . 2H(2)O in aqueous solution using the hydrothermal method and characterized by single-crystal X-ray diffraction analysis. X-ray crystallography reveals that 1 is a novel two-dimensional framework material constructed from the mixed AsN polyoxometalates and coordination groups. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：259 / 261

页数：3

共 14 条

[1] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].