Electrochemistry of hypervalent compounds.: 6.: Selective α-fluorination of sulfides using electrogenerated hypervalent p-methoxyiodobenzene difluoride

被引：8

作者：

Fuchigami, T ^{[1
]}

Fujita, T

Higashiya, S

Konno, A

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 226, Japan

[2] Shizuoka Univ, Fac Engn, Joho Ku, Hamamatsu, Shizuoka 432, Japan

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1998年 / 45卷 / 01期

关键词：

direct fluorination; alpha-fluorosulfide; alpha-acylsulfide; hypevalent compound; iodobenzene di-fluoride; Et3N center dot 3HF;

D O I：

10.1002/jccs.199800022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anodically generated hypervalent p-methoxyiodobenezene difluoride reacted with alpha-(arylthio)- and alpha-(benzylthio)acetates, and alpha-(phenylthio)acetophenone to provide the corresponding fluorinated compounds. In all cases, a fluorine atom was introduced exclusively alpha to the ester or benzoyl group.

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页码：131 / 133

页数：3

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