Preparation and characterization of a pseudocapacitor electrode by spraying a conducting polymer onto a flexible substrate

被引:17
作者
Ebrahim, Shaker A. [1 ]
Harb, Mohamed E. [2 ]
Soliman, Moataz M. [1 ]
Tayel, Mazhar B. [2 ]
机构
[1] Univ Alexandria, Inst Grad Studies & Res, Dept Mat Sci, POB 832, Alexandria, Egypt
[2] Univ Alexandria, Fac Engn, Dept Elect Engn, POB 21544, Alexandria, Egypt
关键词
Conducting polymer; Polyaniline; Pseudocapacitors; Flexible electrode; Energy density; POLYANILINE; SUPERCAPACITOR; GRAPHENE; BEHAVIOR;
D O I
10.1016/j.jtusci.2015.07.004
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
070301 [无机化学]; 070403 [天体物理学]; 070507 [自然资源与国土空间规划学]; 090105 [作物生产系统与生态工程];
摘要
In this paper, polyaniline is deposited using a spraying technique onto a flexible current collector for pseudocapacitor applications. The polyaniline is characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and optical absorption studies. The energy density of a pseudocapacitor is higher than that of double-layer supercapacitors due to Faradaic reactions. A high specific capacitance of 594.92 F/g is obtained at a scan rate of 5 mV/s with a scanning potential window of (-0.8 to 0.8 V). The results show an increase in the energy density of 82.63 W h/kg at a potential difference of 1 V using a 4 M potassium hydroxide aqueous electrolyte. (C) 2015 The Authors. Production and hosting by Elsevier B.V. on behalf of Taibah University.
引用
收藏
页码:281 / 285
页数:5
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